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The reduction of roGFP2(S 2 ) is therefore a good example for an enzyme using an alternative reaction pathway to overcome a kinetic challenge, and we hypothesize that other non-glutathione disulfide substrates with reactive proximal cysteinyl residues and rather negative redox potentials also require a ternary complex for their reduction

J Toxicol Environ Health 1996;48:333-48

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When taken as a supplement, glutathione must pass through multiple organs before it can be absorbed into the stream, meaning only a portion of its benefits reach the body